Supervillain groups of Pokesquad

the Venomus 5

 * Ms. Boa (Hynden Walch) - Leader
 * Sting II (Dave Wittenberg) - Second
 * Blitz Toad (Troy Baker) - Scientist
 * Terrible Lizard (James Remar) - Muscle
 * Centepede (Mona Marshall) - Tracker

The Volts Clan

 * The Volter (Travis J. Gould) - Master and Leader of the Volts Clan
 * Lord Vulton (Jeffery Tambor) - Second in command
 * Electromite (Jeff Bennett) - Enforcer
 * Princess Neon (Kari Wahlgren) - Female support of electircity
 * Electron (Vyvan Pham) - Neon's partner
 * Coach Whip (Troy Baker) - Creature

Team Zodiac

 * Val Khan/ Dark Dragon (Greg Cipes) - Leader (Dragon)
 * Viper Jaw (Richard Green) - Second (Snake)
 * Orangutox (Jim Piddock) - muscle (Monkey)
 * Bullet Proof Johnson (Jon Polito) - Enforcement (Pig)
 * Cress Morse/ Cerberus (Dee Bradley Baker) - the Hunter (Dog)
 * Tygris (Jim Cummings) - the Tracker (Tiger)
 * The Pilot (Dee Bradley Baker) - Air borne pirate (rooster)
 * Mad Louie (Bumper Robinson) - Insane whacko (Rabbit)
 * Dr. Abigail Winters (Danica McKeller) - Scientist (Horse)
 * William Haggerd/ The Red Bull (Brad Garrett) - Strength (Ox)
 * Old Man Verroni (Corey Burton) - Eldest of the group (Ram)
 * Stinky Pete (Jim Cummings) - Spy (Rat)